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Garcia-Lodeiro, I.*; Irisawa, Keita; Meguro, Yoshihiro; Kinoshita, Hajime*
Proceedings of 15th International Congress on the Chemistry of Cement (ICCC 2019) (Internet), 10 Pages, 2019/09
The immobilization of low or intermediate-level radioactive wastes in cements is a common practise. Grout, a mixture of Portland cement and supplemental cementitious materials, is commonly used to encapsulate the wastes. However, the conventional cementing process based on portland cement has the risk of hydrogen gas generation, due to the radiolysis of the water intrinsically present in the cement matrix both in the pore solution and the hydrated products. The addition of phosphates to calcium aluminate cement (CAC) is interesting because this system sets and hardens via the acid-based reaction, between the acid phosphate solution and the basic CAC cement. Due to this different mechanism of reaction, it would be possible to generate a solid cementitious product with a reduced water content, which can be beneficial to minimize the risk of hydrogen gas generation associated with the radiolysis of water by radioactive wastes. The present study investigates the effect of water reduction on a phosphate modified CAC systems at different temperatures (35C, 60C, 95C, 110C,180C) in the initial 7 days of curing. Experimental results indicate that these phosphate-based cements do not form the conventional CAC crystalline hydration products in the condition tested, but provide a structural integrity despite a significant amount of water loss. The results also suggest the formation of hydroxyapatite in samples cured at 95C.
Ogikubo, Koji*; Nakano, M.*; Terai, Takayuki*; Yamaguchi, Kenji; Yamawaki, Michio*
Physica C, 357-360(Part.1), p.280 - 283, 2001/09
no abstracts in English
Nakayama, Shinichi; Akimoto, Toshiyuki; Iida, Yoshihisa; Nagano, Tetsushi
Proceedings of International Conference on Scientific Research on the Back-end of the Fuel Cycle for the 21st Century (ATALANTE 2000) (Internet), 4 Pages, 2000/00
no abstracts in English
*; Hanaguri, T.*; *; Maeda, A.*; Sasase, Masato; Hojo, Kiichi; Steel, D. G.*; Lee, J. U.*; Hofman, D. J.*
Physical Review B, 59(17), p.11568 - 11574, 1999/00
Times Cited Count:8 Percentile:45.63(Materials Science, Multidisciplinary)no abstracts in English
Higuchi, Kenji; ; Hasegawa, Yukihiro*
Nuclear Science and Engineering, 127(1), p.78 - 88, 1997/09
Times Cited Count:1 Percentile:14.47(Nuclear Science & Technology)no abstracts in English
*; *; Maeda, A.*; Asaoka, Hidehito; Takei, Humihiko*; *; *; *; *; *; et al.
Journal of the Physical Society of Japan, 65(10), p.3266 - 3273, 1996/00
Times Cited Count:16 Percentile:71.31(Physics, Multidisciplinary)no abstracts in English
Maeda, A.*; *; *; *; *; *; *; Asaoka, Hidehito; *; *; et al.
Journal of the Physical Society of Japan, 65(11), p.3638 - 3645, 1996/00
Times Cited Count:21 Percentile:75.72(Physics, Multidisciplinary)no abstracts in English
*; *; *; *; Morii, Yukio; Shimojo, Yutaka; *
Physica C, 247, p.183 - 188, 1995/00
Times Cited Count:11 Percentile:57.83(Physics, Applied)no abstracts in English
; Masukawa, Fumihiro; Naito, Yoshitaka; *; *
Proc. of the Seminar on SCALE-4 and Related Modular Systems, 0, p.186 - 193, 1994/00
no abstracts in English
; Onodera, Emi*; Masukawa, Fumihiro; Naito, Yoshitaka; Imawaka, Tsuneyuki*; Yoda, Yoshihisa*
JAERI-M 93-128, 50 Pages, 1993/07
no abstracts in English
*; *; *; *; *; *; *; Morii, Yukio; Funahashi, Satoru; *
Physica C, 211, p.409 - 420, 1993/00
Times Cited Count:9 Percentile:49.37(Physics, Applied)no abstracts in English
; Masukawa, Fumihiro; Naito, Yoshitaka; Ido, Masaru*; *
JAERI-M 92-193, 62 Pages, 1992/12
no abstracts in English
Masukawa, Fumihiro; ; Naito, Yoshitaka; *; *
Proc. of the 1st Annual Users Meeting of Fujitsu Parallel Computing Research Facilities, p.P1-A-1 - P1-A-8, 1992/00
no abstracts in English
; Masukawa, Fumihiro; Naito, Yoshitaka; *; Minami, Kazuyoshi*
Journal of Nuclear Science and Technology, 28(12), p.1143 - 1146, 1991/12
no abstracts in English
*; Minami, Kazuyoshi*; ; Masukawa, Fumihiro; Naito, Yoshitaka
Joho Shori Gakkai Kenkyu Hokoku, 91(61), p.25 - 32, 1991/07
no abstracts in English
Shiraishi, Kensuke; ; *
Japanese Journal of Applied Physics, 30(5B), p.L894 - L897, 1991/05
Times Cited Count:7 Percentile:42.67(Physics, Applied)no abstracts in English
*; ; Masukawa, Fumihiro; Naito, Yoshitaka; Minami, Kazuyoshi*
JAERI-M 91-066, 77 Pages, 1991/04
no abstracts in English
Shiraishi, Kensuke; ; *
Japanese Journal of Applied Physics, 30(4A), p.L578 - L581, 1991/04
Times Cited Count:6 Percentile:38.68(Physics, Applied)no abstracts in English
; Masukawa, Fumihiro; Naito, Yoshitaka; *; *
Proc. of the 2nd Fujitsu-ANU CAP Workshop,1991, p.M-1 - M-8, 1991/00
no abstracts in English
Takamura, Saburo; Hoshiya, Taiji;
Applied Physics Letters, 56(16), p.1582 - 1584, 1990/04
Times Cited Count:2 Percentile:17.66(Physics, Applied)no abstracts in English